Self-collisional coupling and broadening in the asymmetric rotor CHF2Cl
Year: 1995
Authors: Cazzoli C., Cludi L., Cotti G., Degli Esposti C., Buffa G., Tarrini O.
Autors Affiliation: Dipartimento di Chimica dell�Universit� di Bologna, Bologna Italy; Dipartimento di Fisica dell�Universit� di Pisa, Pisa Italy
Abstract: The line shape of 15 selected CHF2Cl rotational transitions is studied in the 59�1049 GHz frequency region. Collisional broadening parameters are measured and compared to semiclassical calculations. For some pairs of lines a large collisional coupling effect is observed and analyzed. A semiclassical theoretical model is presented allowing calculations of the coupling parameters in
good agreement with measurements
Journal/Review: JOURNAL OF CHEMICAL PHYSICS
Volume: 102 (3) Pages from: 1149 to: 1156
KeyWords: spectroscopy; pressure broadening; collisional coupling; asymmetric rotor;
DOI: 10.1063/1.469173
Citations: 18
data from “WEB OF SCIENCE” (of Thomson Reuters) are update at: 2025-05-25
References taken from IsiWeb of Knowledge: (subscribers only)
Connecting to view paper tab on IsiWeb: Click here
Connecting to view citations from IsiWeb: Click here
