Self-collisional coupling and broadening in the asymmetric rotor CHF2Cl
Anno: 1995
Autori: Cazzoli C., Cludi L., Cotti G., Degli Esposti C., Buffa G., Tarrini O.
Affiliazione autori: Dipartimento di Chimica dell�Universit� di Bologna, Bologna Italy; Dipartimento di Fisica dell�Universit� di Pisa, Pisa Italy
Abstract: The line shape of 15 selected CHF2Cl rotational transitions is studied in the 59�1049 GHz frequency region. Collisional broadening parameters are measured and compared to semiclassical calculations. For some pairs of lines a large collisional coupling effect is observed and analyzed. A semiclassical theoretical model is presented allowing calculations of the coupling parameters in
good agreement with measurements
Giornale/Rivista: JOURNAL OF CHEMICAL PHYSICS
Volume: 102 (3) Da Pagina: 1149 A: 1156
Parole chiavi: spectroscopy; pressure broadening; collisional coupling; asymmetric rotor;
DOI: 10.1063/1.469173
Citazioni: 18
dati da “WEB OF SCIENCE” (of Thomson Reuters) aggiornati al: 2025-06-22
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