Identical Particles Exchange Symmetry and the Electric Dipole Moment in Molecules
Anno: 2022
Autori: Tino., GM.
Affiliazione autori: Univ Firenze, Dipartimento Fis & Astron, LENS Lab, INFN,CNR INO, Via Sansone 1, I-50019 Sesto Fiorentino, Italy.
Abstract: Based on fundamental symmetries, molecules cannot have a permanent electric dipole moment, although it is commonly used in the literature to explain the different molecular spectra for heteronuclear and homonuclear molecules. Electric-dipole rotational and vibrational spectra can indeed be observed in heteronuclear molecules, while they are missing in molecules with identical nuclei. This paper shows that the missing spectral features can be explained as an effect of the exchange symmetry for identical particles.
Giornale/Rivista: Symmetry-Basel
Volume: 14 (11) Da Pagina: 2397-1 A: 2397-4
Parole chiavi: electric dipole moment; molecular spectra; fundamental symmetries; identical particlesDOI: 10.3390/sym14112397Citazioni: 2dati da “WEB OF SCIENCE” (of Thomson Reuters) aggiornati al: 2025-06-29Riferimenti tratti da Isi Web of Knowledge: (solo abbonati) Link per visualizzare la scheda su IsiWeb: Clicca quiLink per visualizzare la citazioni su IsiWeb: Clicca qui
